Chemistry of Carbon Compounds: 2nd Supplement to 2r.e v.3B, by Malcolm Sainsbury

By Malcolm Sainsbury

Hardbound. a number of extremely important parts of fragrant chemistry are spanned during this quantity. It comprises chapters dedicated to benzoquinones, nitro compounds, metallo derivatives and fragrant hydrocarbons with substituents which include a couple of nitrogen atom, e.g., azobenzenes, azides, and so on.

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Chem. , 1991, 113 709). -G. , Angew. Chem. Int. Ed. M. S. R. Symons, J. Chem. , Chem. , 1993, 1099). An unusual, quantitative, preparation of 1,2-benzoquinone dimethide is by photolysis, in a variety of solvents, of the bisselenoether (110): in situ scavenging with electron-poor alkenes and alkynes affords the corresponding [4 + 2] adducts in 84 - 97% yield (H. Fujihara, M. Yabe and N. Furukawa, J. Org. , 1993, 58, 5291). ~ Se Se (110) (111) (112) Benzo[b]thiete (111) represents a source of 1,2-benzothioquinone monomethide (K.

Chem. Int. Ed. E. C. -Biol. Interactions, 1992, 86, 129). Further, 1,4-benzoquinone monomethides are involved in the sclerotisation (tanning) of insect cuticle (M. , Arch. Insect Biochem. , 1991,279, 145; J. Biol. , 1992, 267, 10355), and in the biosynthesis of melanins (M. Sugumaran, H. Dali and V. Semensi, Bioorg. , 1990, 18, 144) and eumelanins (M. Sugumaran and V. Semensi, J. Biol. , 1991, 266, 6073). R. D. Turnbull, J. Org. M. G. Apushkinskii, Russ. Chem. , 1992, 61,105; E. Tsuchida and K.

E. L. Schilling, J. Org. A. L. N. Korotkova, J. Chem. Res. (S), 1993, 34; H. , J. Chem. , Chem. , 1994, 573] for the 45 development of novel redox systems (K. Takahashi, Pure Appl. 5, 127; K. Takahashi and S. Tarutani, J. Chem. , Chem. , 1994, 519; S. , J. Org. , 1994, 5_99,3077), synthetic metals (T. , Synth. S. J. Epstein, Angew. Chem. Int. Ed. , 1994, 33, 385). Thiobenzoquinones , Few data are available for these often very reactive compounds. The sulfones (119; R = H) (S. , J. Org. , 1985, 50, 2158), and (119; R = CI) and (120) (L.

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